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Effect of Dy substitution upon the electron spin resonance bottleneck of GdAl2

✍ Scribed by Thân-Trong Nguyên; L.B. Chiu; P.R. Elliston; A.M. Stewart; K.N.R. Taylor

Publisher
Elsevier Science
Year
1977
Weight
138 KB
Volume
86-88
Category
Article
ISSN
0378-4363

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The role of alkyl substitution on the sp
The role of alkyl substitution on the spin distribution in the radical cation of alkyl-cyclohexane: An electron-spin-resonance study
✍ Kazumi Toriyama; Kaoru Matsuura; Keichi Nunome 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 475 KB

The role of alkyl substitution on the electronic structure of cyclohexane radical cation was investigated with low-temperature matrix ESR and semiempirical MO calculations. It was found that the unpaired electron, which is originally delocalized throughout the cyclohexane ring, tends to be confined