The effect of diffusivity on gas-side mass transfer coefficient was studied in an experimental bubble column. A fourteen-fold variation of diffusivity was obtained by using a variety of solutes and carrier gases. Both absorption and vaporization experiments were car&d ou< some&es for the same solute
Effect of diffusivity on gas-side mass transfer coefficient
โ Scribed by A. Tamir; J.C. Merchuk
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 375 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0009-2509
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โฆ Synopsis
Abstrac-Expenments conducted In a stirred cell on evaporation of pure bqulds Into various tamer gases yield that the gas-wde NaSS transfer coefficient, 4, IS proportIonal to the bmary dfiusmty, D, ramed to the power 0 684 t-2/3) Ih'TRODUCTION The obJectrve of the present study IS to detemme the exponent n in the relatlonshlp &SD" (1) resultmg from basic models for mass transfer Thus IS achieved from evaporation expenments of pure hqulds into various gases 111 a stirred cell This techmque assures that the gas side resistance 1s the controlhng factor The major advantage of the stured cell over previous devices is its known mterfaclal area for mass transfer Consequently, the true gas-side mass transfer coefficient k. can be determmed rather than an overall coefficient &,a, so that It IS possible to study directly the effect of D on k, According to the film-model, n = 1 The penetration model and the random surface renewal model suggested by Danckwerts predict that n = 0 5, whereas the filmpenetration model[l] predicts that the exponent n may vary from 0 5 to 1 Expertmental results for n m the relationship k,aaD" (21
๐ SIMILAR VOLUMES
A and B fall to zero witlung the film, I e mstantaneous reactrons Tlus range of behavlour has been discussed frequently at some length (e g Danckwerts[2], Astar&@]) It Is therefore clear that the react~oon may proceed supnticantly either m the bulk of the liquid (Fig la-c) or m the liquid tilm (Fg l
The effect of gas flow rate, liquid flow rate and dilfusivity of the solute in the gas-phase on the gas-side mass transfer coefficient was investigated in laboratory packed columns containing + in. (O-95 cm) ceramic Raschig rings. An eight-fold variation in the diffusivity was obtained. It was found
The present work reports a series of' experimental measurements of liquid-side mass transfer coefficient for slugs rising in liquids with viscosities in the range 0.9 x IO-'-0.14 Pas. Three column diameters were used (19,32 and 52 mm) and slugs with values of L/D up to 38 were studied. The data obta
comparison of the values of mterfaclal area m cocurrent downward flow of gas and hquld with those obtamed m upward flow revealed very httle difference Volumetric as well as true hqmd side mass transfer coefficients m downflow were found to be several times lower than m upflow Only m the smallest 10