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EFFECT OF DIELECTRIC CONSTANTS OF SOLVENTS ON THE BATHOCHROMIC SHIFTS IN RETINAL ISOMERS STUDIED THROUGH CARBON-13 NMR AND CNDO/2 METHODS

✍ Scribed by Minoru Sakurai; Isao Ando; Yoshio Inoue; Riichirô Chûjô


Book ID
114893696
Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
622 KB
Volume
34
Category
Article
ISSN
0031-8655

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A CNDO/2 study on the additivity and the
✍ Reino Laatikainen 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 474 KB

## Abstract The general correlation between the electron densities and the ^13^C NMR chemical shifts is found to be quite poor in the cases discussed. The non‐additivities of the substituent effects on the chemical shifts and the CNDO/2 electron densities correlate only weakly. However, when the el