## Abstract Structural modifications of the HoveydaβGrubbs ruthenium metathesis complex __via__ electronic and structural withdrawing of the chelating alkoxy ligand were investigated. By decreasing the donor properties of the oxygen atom, an acceleration in catalytic activity was achieved based on
Effect of Deprotonation of a Benzimidazolyl Ligand on the Redox Potential and the Structures of Mononuclear Ruthenium(II) Complexes
β Scribed by Hongfei Sun; Mei Wang; Kun Jin; Chengbing Ma; Rong Zhang; Licheng Sun
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 122 KB
- Volume
- 2007
- Category
- Article
- ISSN
- 1434-1948
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π SIMILAR VOLUMES
Figure 1. Molecular structures of 1 a-c and [Ru II (bda)(pic) 2 ] (2).
The electronic and EPR spectra of Cu(RC02)2 [R = (CH3)2CH-, C2Hg-,(CH3)$-] have been measured in pyridine-chlorobenzene solvent mixtures. The results have been interpreted in terms of equilibrium between mononuclear and binuclear forms of copper(l1) carboxylate complexes with pyridine. The dimerizat
A new 7,16-bis(quinolin-8-ylmethyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane ligand, L, has been prepared and its crystal structure reported. In addition, the structure of the protonated ligand H 2 L has been determined. H 2 L is of interest because of interatomic interactions between the ligand