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Effect of Counter-Ion on Recycle of Polymer Resin Supported Co(III)-Salen Catalysts in the Hydrolytic Kinetic Resolution of Epichlorohydrin

✍ Scribed by Krishnan Venkatasubbaiah; Xun-Jin Zhu; Christopher W. Jones

Book ID
106549806
Publisher
Springer
Year
2010
Tongue
English
Weight
210 KB
Volume
53
Category
Article
ISSN
1022-5528

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The recyclability of Co(III)-salen catalysts, where salen is defined by (R,R)-N,N -bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediamine, for the hydrolytic kinetic resolution (HKR) of racemic epichlorohydrin is a strong function of the counterion of the Co(III)-salen catalyst. The nature of the