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Effect of copper stearate on the kinetics and mechanism of the bulk polymerization of methyl-methacrylate

✍ Scribed by M.D. Gol'dfein; A.D. Stepukhovich; Ye.I. Cheptsov

Book ID
118357937
Publisher
Elsevier Science
Year
1967
Weight
381 KB
Volume
9
Category
Article
ISSN
0032-3950

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Effect of a Ο€-donor on the radical bulk
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✍ Wiebke Wunderlich; Nick Benfaremo; Markus Klapper; Klaus MΓΌllen πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 317 KB

## Abstract Bulk polymerizations of methyl methacrylate (MMA) at 60Β°C initiated with 2,2′‐azoisobutyronitrile are influenced by the presence of an organic π‐donor such as tetrathiafulvalene (TTF). Upon addition of TTF, the ratio of weight‐ to number‐average molecular weights __MΜ„__~w~/__MΜ„__~n~ are