Recent studies have demonstrated the role of acid-volatile sulfide (AVS) in controlling the bioavailability of several cationic metals in anoxic sediments. However, metal-sulfide complexes can be relatively labile with respect to oxidation associated with factors such as seasonal changes in rates of
Effect of copper on nitrous oxide reduction in freshwater sediment
β Scribed by C. A. Flemming; J. T. Trevors
- Publisher
- Springer Netherlands
- Year
- 1988
- Tongue
- English
- Weight
- 361 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0049-6979
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β¦ Synopsis
The effect of Cu(II) sulfate on N20 reduction was studied in anaerobically incubated freshwater sediment at 15 Β° C. At Cu concentrations from 100 to 5000 gg g-1, a concentration-dependent decrease in sediment pH was observed in conjunction with a decrease in N20 reduction in Cu 2 Γ· treated sediment in flask-microcosms analyzed immediately after metal addition. However, if flask-microcosms were amended with Cu 2+ and then pre-incubated to allow the sediment pH to naturally return to its original pH (7.1), an inhibitory effect was only produced at 5000 gg Cu g-1 sediment. Copper retention studies showed that up to 96.4% of the added Cu 2 Γ· (2500 gg g -l ) was retained by sediment.
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