Effect of cooperativity on the O-H stretching force constant in associated water species
โ Scribed by M. C. Shivaglal; R. Brakaspathy; Surjit Singh
- Book ID
- 112906821
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 1988
- Tongue
- English
- Weight
- 548 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0253-4134
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๐ SIMILAR VOLUMES
Semi-empirical molecular-orbital calculations are reported for the O-H stretching force constants of different hydrogen-bonded species of water involving dimeric, trimeric, tetrameric and pentameric associations. These calculations show that -in general -a water molecule bonded to another water mole
Al1 quadratic, cubicand quartic force constantsassociated with the VF\_H and VF\_H.\_\_O stretching of F-H---OH+ have been computed employing the confiiuratbn interaction approach. The contribution of quadrupole excitations was also estimated. The Y~\_\_~, ZJ~H.. .Q modes and the deuterated analogui
The NMR spectra of solutions of 30% 17 O-enriched H 2 O and D 2 O in nitromethane display the resonances of the three isotopomers H 2 O, HDO, and D 2 O. All 17 O, 1 H and 17 O, 2 H coupling constants and the primary and secondary isotope effects on J( 17 O, 1 H) have been determined. The primary eff