Effect of comonomer hydrophilicity and ionization on the lower critical solution temperature of N-isopropylacrylamide copolymers
β Scribed by Feil, Herman; Bae, You Han; Feijen, Jan; Kim, Sung Wan
- Book ID
- 120548930
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 655 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0024-9297
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This work was done to investigate the effect of three different ionizable components (acrylic acid, AA; itaconic acid, IA; maleic acid, MA) on the volume phase transitions and swelling equilibria of thermoshrinking type N-isopropylacrylamide (NIPAAM) gels in water. NIPAAM copolymer gels were synthes
## Abstract The lower critical solution temperatures (LCSTs) were verified and determined for different molar feed ratios of __N__βisopropylacrylamide (NIPAAm) and 2βhydroxyethyl methacrylate (HEMA) monomers with ultraviolet spectroscopy and differential scanning calorimetry techniques. Increases i
Linear and crosslinked polymers based on N-isopropylacrylamide (NIPAAm) exhibit unusual thermal properties. Aqueous solutions of poly(N-isopropylacrylamide) (PNIPAAm) phase-separate upon heating above a lower critical solution temperature (LCST), whereas related hydrogels undergo a swelling-shrinkin