Effect of cocatalysts on ethylene polymerization with fluorinated bisphenoxyimine titanium as a catalyst
β Scribed by Ting Li; Fan Wang Kong; Ran Liu; Zhi Yun Li; Fang Ming Zhu
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 77 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Different chlorine-free alkylaluminum compounds were active cocatalysts for ethylene polymerization in the presence of 1,4-bis(2,6-diisopropylphenyl)-acenaphthenediimine-dichloronickel (II) (1). The combination of 1 with trimethylaluminum or triisobutylaluminum produced catalytically active species
Ethylene polymerization was carried out with a novel in-situ-supported metallocene catalyst that eliminates the need for a supporting step before polymerization. The influence of the metallocene amount, aluminum to zirconium mole ratio, temperature, pressure, and cocatalyst type on polymerization ki