Effect of cobalt(III) 1-nitroso-2-naphtholate on free-radical polymerization to vinyl monomers

The effect of initiator-to-monomer ratio

The effect of initiator-to-monomer ratio on the properties of the polybutadiene-ol synthesized by free radical solution polymerization of 1,3-butadiene

✍ Gity Mir Mohamad Sadeghi; Jalil Morshedian; Mehdi Barikani 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 133 KB

## Abstract Polybutadiene‐ol was synthesized by solution radical polymerization of 1,3‐butadiene in the presence of hydrogen peroxide as initiator and 2‐propanol as solvent. The ratio of initiator to monomer molar concentration, [I~0~]/[M~0~], was varied while temperature, reaction time and the typ