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Effect of Charge-Transfer Interactions on the Radiative Rate Constant of 1 Δ g Singlet Oxygen

✍ Scribed by Darmanyan, Alexander P.

Book ID
120657126
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
95 KB
Volume
102
Category
Article
ISSN
1089-5639

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Mechanism of singlet oxygen interaction
Mechanism of singlet oxygen interaction with solvent removing prohibition of the radiative 1Δg → 3Σ−g transition in oxygen
✍ Alexander P. Darmanyan 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 564 KB

The values of relative 0s ('A,) luminescence rate constant (kp ) in thirty-two solvents with ionization potentials IP = 8-l 1 eV are satisfactorily described by a linear dependence of log (kp /n 2, versus IP with a slope of -0.30 eV-i. Singlet oxygen acting as an electron acceptor forms a loose exci