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Effect of channel geometry on solute dispersion in pressure-driven microfluidic systems

✍ Scribed by Debashis Dutta; Arun Ramachandran; David T. Leighton


Publisher
Springer-Verlag
Year
2006
Tongue
English
Weight
492 KB
Volume
2
Category
Article
ISSN
1613-4982

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The classical Stranks-Hush-Marcus theory of pressure effects on the rates of outer-sphere electron transfer reaction rates in solution underestimates IzaV\*[; specifically, for the MnO4/MnO24 (aq) exchange, zaV\*=-21.2 (observed) vs. -6.6cm 3 mol 1 (calculated). This discrepancy can best be resolved