✦ LIBER ✦

Effect of cavity surface on S2 emission in molecular emission cavity analysis

✍ Scribed by Koichi Nakajima; Kyuji Ohta; Takeo Takada

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 784 KB
Volume: 270
Category: Article
ISSN: 0003-2670
DOI: 10.1016/0003-2670(92)80114-m

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✦ Synopsis

Alkali metal salts present in distilled water as impurities change the surface of a silica cavity from smooth to rough and groovy surface. The multi-peaked responses observed with a new cavity change into a single peak when the cavity is treated with alkali metal salts compounds. It is concluded that the effect of the alkali metal salt-treated cavity is mainly attributable to the roughness of the surface; the peak splitting is caused by aggregate formation and the roughness of the cavity surface enhances good dispersion and volatility of samples and suppresses peak splitting.

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