Photoinduced hydrogen evolution with hydrogenase from Desu&ouibrio culgaris (Miyazaki) by the combination of three component system consisting of triethanolamine, zinc-tetraphenylporphyrin tetrasulfonate (ZnTPPS,) znd methyl viologen was irsvestigated in c.%lonic surfactant, cetyltrimethy!ammonium b
Effect of cationic surfactant on photoinduced hydrogen evolution with hydrogenase
β Scribed by Yutaka Amao; Ichiro Okura
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 270 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1381-1169
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β¦ Synopsis
Photoinduced hydrogen evolution with hydrogenase by use of a three component system consisting of triethanolamine, zinctetraphenylporphyrin tetrasulfonate (ZnTPPS,) and methyl viologen was investigated in cationic surfactant, cetyltrimethylammonium bromide (CTAB). In the presence of CTAB, the lifetime of reduced methyl viologen and ZnTPP!$ cation radical increased and effective hydrogen evolution from reduced methyl viologen with hydrogenase was accomplished.
π SIMILAR VOLUMES
## Ahtract -The effect of electrode surface roughness on the kinetics of the hydrogen evolution reaction has been studied for mild steel and nickel cathodes in 10 M NaOH at 348 0 K. With the nickel cathodes, the 'T'afel slope was independent of whether the electrode surface was smooth or roughened