Effect of calcination temperature on catalyst reducibility and hydrogenation reactivity in rice husk ash–alumina supported nickel systems
✍ Scribed by Feg-Wen Chang; Maw-Suey Kuo; Ming-Tseh Tsay; Ming-Chung Hsieh
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2004
- Tongue
- English
- Weight
- 383 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0268-2575
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✦ Synopsis
Abstract
Nickel catalysts supported on rice husk ash–alumina (Ni/RHA–Al~2~O~3~) were prepared by an incipient wetness impregnation method. Characterization included TGA, DSC, TPR, XRD, and BET. Results show that the decomposition of the nickel compound to nickel oxide was complete above 500 °C. The TPR analysis revealed a strong interaction between nickel and support, and a decrease in reducibility of NiO with increasing calcination temperature. The XRD analysis of Ni/RHA–Al~2~O~3~ catalyst precursors demonstrated the presence of spinel. It also showed that the size of crystallites in the supported NiO first decreased with increase in calcination temperature up to 700 °C, and then increased due to phase transformation of nickel oxide to spinel. The pores are mesopores and their meshy surface structure was not affected by calcination temperature in the range investigated. The catalytic activity was tested by CO~2~ hydrogenation with an H~2~/CO~2~ ratio of 4/1 at 500 °C. The CO~2~ conversion and CH~4~ yield for CO~2~ hydrogenation over 15 wt% Ni/RHA–Al~2~O~3~ catalyst were almost independent of calcination and reduction temperatures. Copyright © 2004 Society of Chemical Industry