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Effect of an inhomogeneity on local chain dynamics: conformational autocorrelation function

โœ Scribed by Veissier, Valerie; Viovy, Jean Louis


Book ID
126934334
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
641 KB
Volume
21
Category
Article
ISSN
0024-9297

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## Abstract **Summary:** Nonrandomness in the distribution of rotational isomeric states along a flexible unperturbed chain reduces its conformational entropy. Pairwise interdependence of the bonds is a necessary, but not sufficient, condition for a significant reduction. The reduction in conformat