Effect of allylic substituents on the face selectivity of Diels-Alder reactions of semicyclic dienes
โ Scribed by Datta, S. C.; Franck, R. W.; Tripathy, R.; Quigley, G. J.; Huang, L.; Chen, S.; Sihaed, A.
- Book ID
- 120557444
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 988 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
An internal Diels-Alder reaction, using furan as the diene component, formed a highly functionalized 5-membered carbocycllc ring in excellent yield. Solvent and substituent effects of this reaction were examined. In connection with a proJect devoted to the synthesis of some natural products contai
Face selectivity of Diels-Alder reaction of diene having the stereogenic center at allylic position depends on dienophile polarity, and hetero Diels-Alder reaction with dienophile such as N-tosylimine and Ntosylsulfinylimine was found to give exclusively ul product. The reaction mechanism and empiri