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Effect of alkali metal cations on the structure of Mo(VI)SiO2 catalysts and its relevance to the selective oxidation of methane and methanol

✍ Scribed by Miguel A. Bañares; Nicholas D. Spencer; Michael D. Jones; Israel E. Wachs

Book ID
113180712
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
553 KB
Volume
146
Category
Article
ISSN
0021-9517

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The role of alkali metal promoters (Li, Na, K, Cs) in the c~ and/3 phases of NiMoO4 for butane oxidative dehydrogenation (ODH) was studied. The catalysts were characterized by BET, ICP, Xray fluorescence, AA, XRD, TG, DSC, IR, and XPS techniques. It was evidenced that the added alkali metals are dep