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Effect of ageing in Ni–Fe–Ga ferromagnetic shape memory alloys

✍ Scribed by J. Font; J. Muntasell; R. Santamarta; F. Masdeu; J. Pons; E. Cesari; C. Seguí; J. Dutkiewicz


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
953 KB
Volume
438-440
Category
Article
ISSN
0921-5093

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✦ Synopsis


Three polycrystalline Ni 53.5+x -Fe 19.5-x -Ga 27.0 alloys, with x = 0, 0.5, 1.5 (at.%), have been aged at 520 and 670 K. The initial increase of martensitic transformation temperatures upon ageing has been attributed to a decrease of L2 1 order. The alloys with lower Fe content show remarkable thermal stability for ageing times larger than 10 7 s at 520 K. In the case of ageing at 670 K, degradation of the alloys occurs after ∼10 6 s. Optical and transmission electron microscopy reveal the initial presence of ␥ particles mostly located at the grain boundaries, as well as the appearance of small (<1 m) elongated precipitates after long ageing periods at 670 K, associated to a drop of transformation temperatures.


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