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Effect of adsorbents on the leachability of cement bonded electroplating wastes

✍ Scribed by F.D. Tamás; L. Csetényi; J. Tritthart


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
323 KB
Volume
22
Category
Article
ISSN
0008-8846

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✦ Synopsis


This study is aimed at the determination of pore solution composition of hardened cement pastes prepared with the addition of chromium-, cadmium-and nickel-salts. Due to the high pH-value of the pore water of cement paste, cadminm and nickel were transformed into insoluble hydroxides and precipitated practically quantitatively. Chromium, added as Na2Cr207.2 H20, which is soluble in a highly alkaline medium, was partly bound. It is not clear yet, whether chromium was adsorbed and/or incorporated in hydration products. The use of clinker instead of cement caused a more intensive bond. Adsorbents (silica fume, fly ash and activated carbon), with the exception of fly ash did not improve this bonding.


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Curing temperature was found to dramatically affect the amount of waste leached from a solidified waste/cement matrix between 2 and 40°C. Using lead nitrate as a model waste, samples cured for 7, 14, and 28 days at a cure temperature of 40°C leached very little lead (1-3 mg/liter), while at a cure t