Effect of additives on photocrosslinking of poly(2, 3-epithiopropyl methacrylate)
✍ Scribed by Egawa, H. ;Nonaka, T. ;Tokushige, K. ;Tsunooka, M. ;Tanaka, M.
- Publisher
- John Wiley and Sons
- Year
- 1983
- Weight
- 221 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0360-6376
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## Abstract Poly(2,3‐epithiopropyl methacrylate) (PETMA) has an absorption maximum at 258 nm (ε~max~ = 50) in dioxane which is due to episulfide groups. When irradiated at 254 nm under atmospheric pressure its film became insoluble. When kept at 70°C for several minutes a PETMA film became partiall
## Abstract We report first results on the controlled radical polymerization of 2,3‐epithiopropyl methacrylate (ETMA) also known as thiiran‐2‐ylmethyl methacrylate. Reversible addition‐fragmentation chain transfer (RAFT) of ETMA was carried out in bulk and in solution, using AIBN as initiator and t
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