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Effect of a remote ligand substituent on premature β-H elimination in a cobaloxime-mediated radical alkyl-alkenyl cross coupling

✍ Scribed by Bruce P. Branchaud; Youngshin Lee Choi


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
118 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis


The dpgH (diphenylglyoxime monoanion) ligand suppresses premature ,9-H elimination compared to the standard cobaloxime ligand dmgH (dimethylglyoxime monoanion).

In this paper we report studies of cobaloxime-mediated radical alkyl-alkenyl cross couplings 2*3 of 20 mM CH3(CH2)8CH2Co111(dmgH)2py