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Effect of a C7.pi.-electron donor on a cycloheptatriene-norcaradiene equilibrium

✍ Scribed by Staley, Stuart W.; Fox, Marye Anne; Cairncross, Allan


Book ID
126061385
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
365 KB
Volume
99
Category
Article
ISSN
0002-7863

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The photochemistry of cycloheptatrienes
✍ A.R. Brember; A.A. Gorman; J.B. Sheridan πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 French βš– 193 KB

The light induced ring closure of cycloheptatrienes to bicycle-[3,2,0]-hepta-2,6-dienes is generally directionally specific in those cases where theoretically two bicyclic products may be formed (1). We have recently rationalised this fact in terms of the effect of eubstituents on the dirdction of p