Treatment of methyl 13(S)-hydroperoxy-9(Z),ll(E)-octadecadienoate with vanadium oxyacetylacetonate led to the formation of two diastereomeric ~,#-epoxy alcohols, i.e. methyl ll(R),12(R).epoxy-13(S)-hydroxy-9(Z)-octadecenoate and methyl ll(S),12(S)-epoxy-13(S)hydroxy-9(Z)-octadecenoate. The epoxy alc
Effect of 13-hydroperoxy-9,11-octadecadienoic acid (13-hpode) on arachidonic acid metabolism in rabbit platelets
โ Scribed by Fujimoto Yohko; Sumiya Toshiki; Tsunomori Masahide; Nlshida Hlroko; Sakuma Satoru; Fujita Tadashi
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 482 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0020-711X
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๐ SIMILAR VOLUMES
In the presence of oxygen, UV-irradiation of a solution of methyl 13(S)-hydroperoxy-9(Z), 1 l(E)-octadecadienoate (13-HPOD) in cyclohexane leads to a broad pattern of reaction products of which a trihydroxyene, seven epoxyhydroxides, four hydroxydienes, four epoxyhydroperoxides, six oxodienes and an
A solution of methyl 13(S)-hydroperoxy-9(Z),ll(E)-octadecadienoate (13-HPOD)in methanol was irradiated under anaerobic conditions at 15ยฐC with light at wavelengths greater than 230 nm. After 2 h the 13-HPOD was completely degraded and four major products were formed. Three of them were identified as
in the presence of oxygen, UV-irradiation of a solution of methyl 13(S)-hydroperoxy-9(Z),l I(E)octadecadienoate (13-HPOD) in methanol yields stereoisomers of methyl 9,13-dihydroxy-10methoxy-1 l(E)-octadecenoate and methyl 9,13-dihydroxy-12-methoxy-10(E)-octadecenoate as major products. The reaction