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(E,E)-1-methoxy-4-trimethylsilyl-1,3-butadiene: a diene for the diels-alder synthesis of methoxy-substituted allyl silanes

✍ Scribed by J.J. Pegram; C.B. Anderson


Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
133 KB
Volume
32
Category
Article
ISSN
0040-4039

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The synthesis of 1-benzyldimethylsilyl-4
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1-Benzyldimethylsilyl-4-phenylthio-1,3-butadiene (L), prepared by hydrosilation of propargyl alcohol, oxidation and followed by Wittig-Horner reaction, underwent Diels-Alder reaction with methyl methacrylate. The adduct after oxidation to the sulfone when treated with fluoride gave 5-carbomethoxy-5-