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Eclipsed exocyclic carbon-oxygen bonds in the hexamethyl ether of scyllo-inositol. X-ray crystallographic and NMR studies

✍ Scribed by J.Edgar Anderson; Stephen J. Angyal; Donald C. Craig


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
373 KB
Volume
272
Category
Article
ISSN
0008-6215

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✦ Synopsis


Hexa-O-methyl-scyllo-inositol was synthesized and its crystal structure was determined by X-ray diffraction. As predicted by calculations, each oxygen-methyl bond eclipses the adjacent carbon-hydrogen bond. NMR studies show that the same conformation predominates in solution.