✦ LIBER ✦
Echo-detected ESR spectroscopy with magnetic field vector jumps: A novel approach for improving the spectral resolution in disordered systems
✍ Scribed by Susanne Pfenninger; A. Schweiger; J. Forrer; R.R. Ernst
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 547 KB
- Volume
- 151
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
A novel time-domain ESR technique for enhancing the resolution of powder spectra is presented. The selection of specific crystallite orientations is based on single or double jumps ofthe magnetic field vector in the time between the microwave pulses of standard two-or three-pulse echo sequences. The performance of the approach is exemplified by applications to transittonmetal complexes in disordered systems.