Antiferromagnetic complexes involving me
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A.A. Pasynskii; I.L. Eremenko; B. Orazsakhatov; Yu.V. Rakitin; V.M. Novotortsev;
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Article
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1980
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Elsevier Science
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English
⚖ 664 KB
The complex, (CpctSCMe~)zS (I), contains a Cr-Cr bond (2.689 A) and at the same time shows antiferromagnetic properties (-2J = 430 cm-'). It reacts with PhEH (E is S, Se) or MeI to give binuclear complexes (CpCrEPh)$ or [(CpCrSCMe,),SMe] 'Icharacterized by exchange parameter, -23. values of 496, 378