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Easy and stereoselective synthesis of the phosphono analogue of α-L-rhamnose 1-phosphate

✍ Scribed by Laura Cipolla; Barbara La Ferla; Francesco Nicotra; Luigi Panza

Book ID: 104257599
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 116 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)01245-8

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✦ Synopsis

The C-glycosidic analogue of ct-L-rhamnose l-phosphate has been stereoselectively synthesised reacting 2,3,4-tri-O-benzyl-L-rhamnopyranose with tetraethyl methylenediphosphonate and sodium hydride in diglyme, and then deproteeting with iodotrimethylsilane.

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