The bond lengths in the title compound, C 13 H 11 N 3 O 2 ÁH 2 O indicate that the organic molecule exists in the keto form. A network of O-HÁ Á ÁO, O-HÁ Á ÁN and N-HÁ Á ÁO hydrogen bonds helps to consolidate the crystal packing.
(E)-N′-(4-Fluorobenzylidene)isonicotinohydrazide monohydrate
✍ Scribed by Chen, Shi-Kun
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 185 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The asymmetric unit of the title compound, C~14~H~13~N~3~O~3~·H~2~O, contains one molecule of __N__′-(4-hydroxy-3-methoxybenzylidene)isonicotinohydrazide and one solvent water molecule. The crystal packing is stabilized by O—H...N and O—H...O hydrogen bonds.
The title compound, C 13 H 11 N 3 O 2 , was prepared by the reaction of pyridine-4-carboxylic acid hydrazide and phydroxybenzaldehyde in ethanol. In the crystal structure, all non-H atoms are coplanar, with an r.m.s. deviation of 0.096 A ˚. N-HÁ Á ÁN, O-HÁ Á ÁN and O-HÁ Á ÁO intermolecular hydrogen
In the title compound, C 20 H 16 ClN 3 O 2 , the central benzene ring makes dihedral angles of 68.91 (5) and 60.23 (5) with the chlorobenzene ring and the pyridine ring, respectively. The packing is stabilized by intermolecular N-HÁ Á ÁO hydrogen bonds and weak, non-classical intermolecular C-HÁ Á Á