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(E)-5-[(2-Fluoro­phen­yl)diazen­yl]-2-hydr­oxy-3-methoxy­benzaldehyde

✍ Scribed by Şahin, Onur ;Albayrak, Çiğdem ;Odabaşoğlu, Mustafa ;Büyükgüngör, Orhan

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
187 KB
Volume
61
Category
Article
ISSN
1600-5368

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(E)-5-[(3-Bromo­phen­yl)diazen­yl]-2-hyd
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✍ Şahin, Onur ;Albayrak, Çigˇdem ;Odabaşogˇlu, Mustafa ;Büyükgüngör, Orhan 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 247 KB

The title structure, C 14 H 11 BrN 2 O 3 , displays the characteristic features of azobenzene derivatives. The two aromatic rings are nearly coplanar, forming a dihedral angle of 8.71 (12) . There is a strong intramolecular O-HÁ Á ÁO bond, and weakand C-HÁ Á Á interactions stabilize the structure.

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In the title compound, C 16 H 13 ClN 2 O 2 , the dihedral angle between the pyridine and benzene rings is 40.1 (1) . There is a weak intramolecular C-HÁ Á ÁCl interaction. Molecules are linked via O-HÁ Á ÁN hydrogen bonds, forming chains of graph-set motif C(6) along the a axis.

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✍ Khanum, S. A. ;Mahendra, M. ;Shashikanth, S. ;Doreswamy, B. H. ;Sridhar, M. A. ; 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 246 KB

In the title compound, C 15 H 14 ClO 2 , the dihedral angle between the two benzene rings is 57.37 (12) .