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(E)-4-Bromo-2-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-ylimino)meth­yl]-6-methoxy­phenyl 4-methyl­benzene­sulfonate N,N-dimethyl­formamide solvate

✍ Scribed by Shi, Jun

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
180 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

Single-crystal X-ray study T = 294 K Mean (C-C) = 0.006 A Disorder in solvent or counterion R factor = 0.046 wR factor = 0.133 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

📜 SIMILAR VOLUMES

(E)-4-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-d
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In the title compound, C 25 H 23 N 3 O 5 S, the vanillin group makes dihedral angles of 1.42 (11), 63.76 (10) and 51.00 (10) , respectively, with the pyrazolone ring, the phenyl ring attached to the sulfonyl group, and the phenyl ring attached to the pyrazolone ring. The crystal packing is governed

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In the title compound, C 25 H 23 N 3 O 4 S, the central benzene ring makes dihedral angles of 8. 73 (3), 68.16 (7) and41.67 (7) with the pyrazolone ring, the sulfur-bound benzene ring and the phenyl ring, respectively. The crystal packing is stabilized by a weak non-classical intermolecular C-HÁ Á Á

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✍ Chen, Xin ;Yu, Ming 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 121 KB

In the title compound, C 27 H 27 N 3 O 5 S, the salicylaldehyde group makes dihedral angles of 20.47 (8), 43.28 (7) and 62.56 (7) with the pyrazolone ring, the methyl-substituted benzene ring and the phenyl ring, respectively.

4-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihy
4-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]benzoic acid methanol solvate
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The title compound, C 19 H 17 N 3 O 3 ÁCH 3 OH, was synthesized by the reaction of 4-amino-1,5-dimethyl-2-phenyl-1,2-dihydropyrazol-3-one and 4-formylbenzoic acid in methanol solution. As expected, the antipyrine derivative adopts a trans configuration about the central C N bond. In the crystal stru