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(E)-4-(4-Ethyl­phenyl­diazen­yl)-2,6-dimethylphenyl acrylate

✍ Scribed by Uçar, Ibrahim ;Kocaokutgen, Hasan ;Özk˙inal˙i, Sevil ;Gür, Mahmut ;Büyükgüngör, Orhan


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
122 KB
Volume
63
Category
Article
ISSN
1600-5368

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The molecule of the title compound, C 15 H 14 N 2 O 2 , is approximately planar and displays a trans configuration with respect to the N N double bond. The dihedral angle between the two aromatic rings is 10.90 ( 14) . The molecules are stacked via weak C-HÁ Á Á interactions.

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The molecule of the title compound, C 14 H 12 N 2 O 2 , is nearly planar and displays a trans configuration with respect to the N N double bond, as found for other diazene derivatives. There is an intramolecular O-HÁ Á ÁO hydrogen bond and the crystal packing is governed bystacking.

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A view of (I), with the atom-numbering scheme and 50% probability displacement ellipsoids for non-H atoms. The intramolecular hydrogen bond is shown as a dashed line.

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In the title structure, C 16 H 16 N 2 O 3 , the benzene rings are in a trans configuration with respect to the azo double bond and the molecule is essentially planar.