In the title compound, C 15 H 19 NO 2 , inversion-related molecules are linked into dimers by interactions between the hydroxyl groups and the nitrile groups. C-HÁ Á ÁO hydrogen bonds join the dimers into an infinite ladder-like chain.
✦ LIBER ✦
(E)-1-(Diphenylphosphinyl)-2-(1-hydroxycyclohexyl)ethene
✍ Scribed by Yu, Bin ;Wang, Xiao-Qing ;Shen, Guang-Qiu ;Shen, De-Zhong
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 725 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The molecule of the title compound, C 20 H 23 PO 2 , displays an E configuration about the C C bond. The two phenyl rings are nearly perpendicular to each other with a dihedral angle of 80.09 (8) . Intermolecular O-HÁ Á ÁO hydrogen bonding and stacking between parallel benzene rings of adjacent molecules, with a iperpendicular distance of 3.4928 (3) A ˚, help to stabilize the crystal structure.
Related literature
For general background, see: Brunner & Limmer (1991). For synthesis, see: Niu et al. (2007).
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