In the structure of the title compound, C 9 H 13 ClN 4 O, the guanidinium group is nearly coplanar with the 2-methoxyphenyl ring, C N having E geometry. The chloride ions are involved in intermolecular hydrogen bonds with the H atoms of the aminoguanidinium ion.
(E)-1-[(2-Chlorophenyl)methyleneamino]guanidinium chloride
✍ Scribed by Sonar, Vijayakumar N. ;Ring, Joshua R. ;Siegler, Maxime ;Crooks, Peter A.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 104 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, C~11~H~13~NO~3~, the methoxycarbonyl group is rotated out of the plane of the 4-methoxybenzyl group. The conformation found in the crystal structure differs from that computed __in vacuo__, where the two groups are coplanar. The crystal structure is stabilized by van der Waals
The title compound, C 20 H 15 ClN 2 O 3 , displays a trans configuration with respect to the C N double bond. The crystal structure is stabilized by intramolecular O-HÁ Á ÁN and N-HÁ Á ÁO and intermolecular O-HÁ Á ÁO hydrogen bonds.
The geometrical parameters for the title compound, C 16 H 13 ClOS, are normal. The dihedral angle between the two benzene rings is 48.16 (5) . The non-centrosymmetric crystal packing is consistent with the substantial non-zero second harmonic generation response.
The title compound, [Fe(C 5 H 5 )(C 19 H 15 ClN)], a new ketiminecontaining ferrocenyl derivative, has been synthesized and characterized structurally. Conjugation between the two benzene rings and the imine group is not observed. In addition, there are no significant intermolecular interactions.