Dynamics of vibrational energy exchange in collisions of OH and OD radicals with N2. Application to the kinetics of OH-vibrational deactivation in the upper atmosphere

Vibration–Internal Rotation–Overall Rota

Vibration–Internal Rotation–Overall Rotation Interactions in CH2DOH and CHD2OH: I. Development and Application of the Separation Transformations to the Zeroth-Order Kinetic Energy

✍ C.Richard Quade 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 329 KB

The zeroth-order kinetic energy is developed for the vibrating-rotating-internally rotating CH(2)DOH and CHD(2)OH molecules using the general theory of Guan and Quade for the vibration-rotation-large amplitude internal motion interactions in molecules. A T transformation is applied to obtain the nec