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Dynamics of the YSZ-Pt interface

✍ Scribed by L. Bay; T. Jacobsen

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
600 KB
Volume
93
Category
Article
ISSN
0167-2738

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✦ Synopsis

Yttria stabilized zirconia (YSZ)-Pt point electrodes were examined by linear potential sweep, potential step and impedance measurements at IoW'C in air. Inductive loops and hysteresis phenomena with long relaxation times were found. Atomic force microscopy showed changes of the interface between Pt and YSZ induced by the current passage. These changes involve transport of solid and are slow enough to explain the large time constants. The low frequency capacitance and inductive loop forming an entire circle indicate the presence of gas reservoirs at the YSZ-Pt interface.

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