Dynamics of the helix-coil transition in poly-L-ornithine
✍ Scribed by Hammes, Gordon G.; Roberts, Peter B.
- Book ID
- 126290837
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 606 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The enthalpy change associated with the isothermal pH-induced uncharged coil-to-helix transition AH; in poly(L-ornithine) in 0.1 N KCl has been determined calorimetrically to be -1530 f 210 and -1270 f 530 cal/mol a t loo and 25OC, respectively. Titration data provided information about the state of
## Abstract The helix–coil transition of poly‐γ‐__N__‐carbobenzoxy‐L‐α,γ‐diaminobutyrate (PCLB) and poly‐δ‐__N__‐carbobenzoxy‐L‐ornithine (PCLO) in chloroform–dichloroacetic acid mixtures was followed by optical rotatory dispersion. PCLB displays a “normal” temperature‐induced transition, but PCLO