Dynamics of Poly(vinyl acetate) in Bulk and on Silica
β Scribed by Blum, Frank D.; Xu, Gu; Liang, Minghua; Wade, Charles G.
- Book ID
- 126076471
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 184 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
## Abstract The effect of diluents and temperature on segmental motion in poly(vinyl acetate) was investigated by both NMR and ESR spectroscopy. Three classes of diluents were studied: chloroform, a thermodynamically good solvent; water, a poor solvent which slightly swells the polymer and lowers i
## SYNOPSIS Poly(viny1 acetate) (PVAc) was incorporated into silica gel using the sol-gel process involving tetraethoxysilane (TEOS) . In order to prepare silica-gel microhybrids, two different processes were employed, and the physical properties of the resulting two sets of hybrids were compared.
## Abstract A crosslinked network was formed by the reaction of partially saponified poly(vinyl acetate) and toluylene diisocyanate in benzene. The yield of gel was markedly dependent on the degree of saponification and the concentrations of polymer and diisocyanate. Crosslinked poly(vinyl alcohol)