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Dynamics of Isobutane inside Zeolite ZSM-5. A Study with Deuterium Solid-State NMR

✍ Scribed by Stepanov, Alexander G.; Alkaev, Maxim M.; Shubin, Alexander A.; Luzgin, Mikhail V.; Shegai, Timur O.; Jobic, Hervé

Book ID
127196073
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
98 KB
Volume
106
Category
Article
ISSN
0022-3654

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Deuterium solid-state NMR study of the m
Deuterium solid-state NMR study of the molecular mobility and dehydration of tert-butyl alcohol on zeolite H-ZSM-5
✍ Alexander G. Stepanov; Alexander G. Maryasov; Vyacheslav N. Romannikov; Kirill I 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 721 KB

## Abstract The molecular mobility and dehydration reaction of __tert__‐butyl alcohol, selectively deuteriated in the methyl groups (__t__‐BuOH[2 – ^2^H~9~], dTBA), absorbed on H‐ZSM‐5 zeolite was studied using ^2^H NMR spectroscopy. At 173–298 K two modes of fast anisotropic motion were observed f