Dynamics of ion solvation in electrolyte solutions: dependence on salt concentration
β Scribed by Amalendu Chandra
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 499 KB
- Volume
- 244
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
A theoretical analysis of the effects of salt concentration on solvation dynamics in electrolyte solutions is presented. The theory includes properly the inertial and non-Markovian effects of ions and solvent molecules. A detailed analysis is made of the short-time and long-time parts of the relaxation of the ion-solution interaction energy and the dependence on salt concentration is discussed. The theoretical predictions are found to be in qualitative agreement with the results of computer simulations.
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Abshact-In order to throw light on ion-solvent interactions, the salvation numbers of electrolytes in different mixed solvents (methanol + water and ethanol + water mixtures) have been determined using ultrasonic interferometer. The anomalies in the salvation number of cations (in aqueous solutions)