Analysis of the muon spin rotation (@R) data for the muonic ethyl radical CH,MucH, yields &hyperfine coupling constants in good agreement with the recent level-crossing resonance (LCR ) measurements. Other coupling constants are predicted and await confirmation by LCR. The role of hyperconjugation i
Dynamics of free radicals observed by muon spin rotation
โ Scribed by E. Roduner
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 302 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0022-2860
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The direct measurement of reorientational rates for hydrocarbon radicals in zeolites is presented, specifically cyclohexadienyl in zeolite X, using a muon spin relaxation method. The method allows discrimination between different adsorption sites and the determination of activation energies for surf
By addition of the light hydrogen isotope muonium (Mu =w'e-) the, l-ethyl-hexen-1-yl radicals CH, = CHCH2CH2CH2CHCH2Mu, CH, = CHOCH,CH,CHCH,Mu, and CH, = CHCH2CH20CHCH,Mu are generated in liquids. Their Fourier transform muon spin rotation spectra show linewidths increasing with increasing temperatu