Dynamics of Chemical and Charge-Transfer Reactions of Molecular Dications. IV. Proton Transfer and Reactions of Dication Isomers in the CHCl 2+ + D 2 System
✍ Scribed by Roithová, Jana; Žabka, Ján; Hrušák, Jan; Thissen, Roland; Herman, Zdenek
- Book ID
- 126418496
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 157 KB
- Volume
- 107
- Category
- Article
- ISSN
- 1089-5639
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A three-dimensional quantum-mechanical study of the (Ar + Hz)+ system within the reactive infinite-order sudden approximation is presented. All four possible channels for chemical reaction and charge transfer were treated simultaneously. The various cross sections deviate by at most 50% from recent
## Abstract The competition between proton and electron transfer in reactions of mass‐selected dications CHX^2+^ (X=F, Cl, Br, and I) with rare gas atoms (Ne, Ar, Kr, and Xe) and selected molecular reagents (N~2~, O~2~, CO, H~2~O, and HCl) is studied in the gas phase. In the ion–molecule reactions