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Dynamics and Extent of Ligand Exchange Depend on Electronic Charge of Metal Nanoparticles

✍ Scribed by Song, Yang; Murray, Royce W.

Book ID
120624855
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
73 KB
Volume
124
Category
Article
ISSN
0002-7863

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but an unusually large second solvation shell such as Au(I). Investigations of metal ions coordinated to ammonia ligands have shown that coordination to hetero-atoms can accelerate the ligand exchange reaction rates by several orders of magnitude, e.g. for Cu(II) and Ni(II). Simulations of ions in a