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Dynamics and a Unified Understanding of Competitive [2,3]- and [1,2]-Sigmatropic Rearrangements Based on a Study of Ammonium Ylides

✍ Scribed by Biswas, Bibaswan; Collins, Sean C.; Singleton, Daniel A.


Book ID
124071599
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
853 KB
Volume
136
Category
Article
ISSN
0002-7863

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[1,3]-Sigmatropic Rearrangements of Divi
✍ Dirk Sperling; Hans-Ulrich Reißig; JΓΌrgen Fabian πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 281 KB πŸ‘ 2 views

Two possible types of competing [1,3] rearrangements of hydroxy and formyl (donor and acceptor) groups in specific positions have also been considered. On the basis of these divinylcyclopropane derivatives and of the hetero-analogous compounds vinylcyclopropanecarbaldehyde and vinylcyclo-calculation