The hot H atom reaction, H+O>-OH t 0, has been studied at a center-of-mass collision energy of 1.6 eV. H atoms were generated by 266 nm photolysis of HI in a mixture of HI and O2 at 293 K. The OH product was probed by laser-induced fluorescence and the nascent OH vibrational, rotational, and fine st
Dynamical bottleneck in the reaction H+O2→OH+O at high collision energies
✍ Scribed by Kleinermanns, K.; Linnebach, E.; Pohl, M.
- Book ID
- 120268888
- Publisher
- American Institute of Physics
- Year
- 1989
- Tongue
- English
- Weight
- 950 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.457026
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The reaction of hydroxyl [OH] radicals with formaldehyde [CH~2~O] was studied at temperatures ranging from 934 K to 1670 K behind reflected shock waves at an average total pressure of 1.6 atm. OH radicals were produced by shock‐heating tert‐butyl hydroperoxide [(CH~3~)~3~COOH], while
Probe-laser-induced ("prompt") reaction of H+ D, was observed in a mixture of HI and D2 using (2 + I ) REMPI detection of the HD product. Rotational distributions for HD(u=O-3) of the prompt reaction are reported here, corresponding to center-ofmass collision energies of I .20-1.65 eV and 1.95-2.40
Pure rotational transitions have been used to probe high rotational states of OH(X 'H, v=O) formed in the reaction H+O+ OH+0 at 2.6 eV collision energy. The infrared diode absorption/gain technique is complementary to laser-induced fluorescence (LIF) and particularly useful for probing those high ro