Dynamic simulation and experimental evaluation of EPDM terpolymerization with vanadium-based catalyst

✍ Scribed by Mônica Carcuchinski Haag; João Henrique Zimnoch dos Santos; Jairton Dupont; Argimiro Resende Secchi

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 242 KB
• Volume: 70
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/(sici)1097-4628(19981107)70:6<1173::aid-app15>3.0.co;2-0

✦ Synopsis

The development of a simplified kinetic model describing some effects observed in catalyzed olefin terpolymerization is presented. Based on the method of moments, the model describes the influence of Al/V ratio and diene concentration on reaction yield and on polymer characteristics such as molecular weight, ethylene incorporation, and polydispersity. In order to verify the model validity, the terpolymerization reactions were performed using VOCl 3 -Al 2 Et 3 Cl 3 systems and 2-ethylidenebicyclo[2.2.1]hept-5-ene (ENB) as diene. The results of dynamic simulation fit well the experimental data for Al/V up to 15, but the model fails under high diene concentration, where branching reactions, neglected by reason of simplification, become significant.