Dynamic potential barrier effects in hyd
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Zhongzhi Yang; Yue Qin; Donald L. Thompson
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Article
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1993
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Elsevier Science
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English
β 447 KB
A simple model is employed to illustrate the influence of the dynamic effective potential resulting from torsional motion on tunneling via bending modes in trans.-& isomerization in polyatomic molecules. We show that the effect is significant and can determine the dominant tunneling mode in systems