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Dynamic parameters of the hypervalent O3B...O bond

✍ Scribed by G. V. Yukhnevich; S. I. Kargov; T. T. Merzlyak


Book ID
105597775
Publisher
Springer
Year
1999
Tongue
English
Weight
404 KB
Volume
48
Category
Article
ISSN
1573-9171

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Revised values of the bond valence param
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## Abstract Bond valence parameters __r__ ~0~ and __b__ have been re-determined for ^[3–11]^Sb(III)–O and ^[6]^Sb(V)–O, utilising crystal structures of natural and inorganic compounds from the Inorganic Crystal Structure Database. Bond valence parameters for Sb(III) were obtained from a best-fit __

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The quadrupole coupling constant (Qcc) and asymmetry parameter (eta) of 11B in crystalline CaO.B2O3 have been measured employing three different NQR and NMR methods: (1) 11B and 10B NQR; (2) 11B NQR and NMR; and (3) the 11B Zeeman NQR powder pattern. It is found that Qcc = 2594.3 +/- 0.5 kHz and eta