Dynamic parameters of the hypervalent O3B...O bond
β Scribed by G. V. Yukhnevich; S. I. Kargov; T. T. Merzlyak
- Book ID
- 105597775
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 404 KB
- Volume
- 48
- Category
- Article
- ISSN
- 1573-9171
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## Abstract Bond valence parameters __r__ ~0~ and __b__ have been re-determined for ^[3β11]^Sb(III)βO and ^[6]^Sb(V)βO, utilising crystal structures of natural and inorganic compounds from the Inorganic Crystal Structure Database. Bond valence parameters for Sb(III) were obtained from a best-fit __
The quadrupole coupling constant (Qcc) and asymmetry parameter (eta) of 11B in crystalline CaO.B2O3 have been measured employing three different NQR and NMR methods: (1) 11B and 10B NQR; (2) 11B NQR and NMR; and (3) the 11B Zeeman NQR powder pattern. It is found that Qcc = 2594.3 +/- 0.5 kHz and eta